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Clayface is an enemy of Batman who uses his shapeshifting abilities to fight Batman. He has fought Superman on multiple occasions.
The Batman[]
In the two-part episodes The Batman/Superman Story Pt. 1 and The Batman/Superman Story Pt. 2, he is hired by Lex Luthor and Black Mask along with Mr Freeze and Bane to defeat Superman, he escapes from the first battle and goes into a sewer, next time he ambushes Batman but is taken down by a flash dehydrator made especially for him.
Final Crisis[]
In the second issue, he triggers an explosion at the Daily Planet which destroys the building and leaves Lois Lane seriously injured.
Supergirl Volume 5[]
Supergirl teams up with Empress to take down Clayface, later on, she helps Robin (Damian Wayne) take down an android mimicking the powers and appearance of Clayface.